Surface modification processes during methane decomposition on Cu-promoted Ni–ZrO2 catalysts

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Surface modification processes during methane decomposition on Cu-promoted Ni–ZrO2 catalysts

The surface chemistry of methane on Ni-ZrO2 and bimetallic CuNi-ZrO2 catalysts and the stability of the CuNi alloy under reaction conditions of methane decomposition were investigated by combining reactivity measurements and in situ synchrotron-based near-ambient pressure XPS. Cu was selected as an exemplary promoter for modifying the reactivity of Ni and enhancing the resistance against coke f...

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ژورنال

عنوان ژورنال: Catalysis Science & Technology

سال: 2015

ISSN: 2044-4753,2044-4761

DOI: 10.1039/c4cy00988f